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<em>复制链接推荐给好友</em></button> <input type="text" class="px vm" onclick="this.select();setCopy(this.value, '链接已经复制到剪贴板');" value="http://forum.oecr.com/plugin.php?id=attachcenter:page&aid=88402" size="50" /></p> </div> <div class="bm"> <div class="bm_c xld"> <b>太阳能电池新型聚合物给体材料的性能研究:</b><div class="postmsg">太阳能电池新型聚合物给体材料的性能研究<br /> Performance of Organic Solar Cell with New Polymer Donor<br /> 下载全文<br /> <br /> 作 者：彭清 雷钢铁 刘煜 朱卫国<br /> PENG Qing, LEI Gangtie, LIU Yu, ZHU Weiguo （Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education ,College of Chemistry,Xiangtan University ,Xiangtan 411105,China）<br /> 机构地区：湘潭大学化学学院环境友好化学与应用教育部重点实验室,湖南湘潭411105<br /> 出 处：《中国材料进展》 CSCD 2015年第34卷第2期 158-162页,143页,共6页<br /> Rare Metals Letters<br /> 基 金：国家自然科学基金（91233112,21172187）; 湖南省自然科学创新研究群体基金（12JJ7002）; 湖南省教育厅重点项目（12A133）<br /> 摘 要：设计合成了新型聚合物给体材料PTT-FTQ,以PTT-FTQ∶PCBM体系作为活性层,研究了给受体比例及膜厚、受体类型、添加剂等因素对有机太阳能电池性能的影响。结果表明,当给受体比例为1∶2时,PTT-FTQ能与受体PC61BM形成良好的网络结构,活性层薄膜表面变得更加光滑平整,在活性层膜厚为120 nm时,有利于吸收光子,传输激子,器件能量转化效率达到2.12%,采用1,8-二碘辛烷（DIO）做添加剂,在添加量为溶剂的1%时,效率提升到2.18%,随着DIO加入量的增加,反而会减少给受体间的界面接触面积,导致激子的解离效率和载流子的传输效率大幅度降低。而采用PC71BM做受体时,电池的短路电流密度比PC61BM体系下的要大得多,但是开路电压会稍低,这主要是PC71BM有较强的光谱吸收但LUMO能级较低,PTT-FTQ∶PC71BM体系能量转化效率达到2.78%。<br /> A new donor material PTT-FTQ for organic solar cell（ OSC） was synthesized and investigated. With the PTT-FTQ∶PCBM as active layer,the factors which influenced the performance of OSC such as the ratio of donor / acceptor,the film thickness of active layer,the various acceptors and the additive were studied and optimized. The results showed that when the ratio of donor / acceptor was 1∶ 2,a better interpenetrating network between PTT-FTQ and PC61 BM was formed and the active layer has a more smooth surface morphology. When the film thickness of active layer was 120 nm,the power conversion efficiency（ PCE） of OSC was 2. 12%. Using 1,8-diiodooctane（ DIO） as the additive,PCE of OSC was 2. 18%. The current density of OSC with PC71 BM as acceptor is much greater than that of PC61 BM while the voltage is slightly lower. This is mainly due to the lower LUMO energy level and stronger spectral absorption of PC71 BM. High PCE of 2. 78% was achieved with PC71 BM as acceptor.<br /> 关键词：有机太阳能电池 聚合物给体 受体 添加剂<br /> organic solar cell ; polymer donor ; acceptor ; additive ;</div> <div style="height200px;"></div> </div> </div> </div> </div></div> </div> <!--autocomment filter by maxnum--> <div class="ft_wp"> <div id="ft" class=" cl"> <div id="flk" > <p> <a href="http://wpa.qq.com/msgrd?V=3&Uin=20600600&Site=光电工程师社区&Menu=yes&from=discuz" target="_blank" title="QQ"><img src="static/image/common/site_qq.jpg" alt="QQ" /></a><span class="pipe">|</span><a href="http://m.oecr.com" >手机版</a><span class="pipe">|</span><a href="http://so.oecr.com" title="站内搜索" target="_blank" >搜索</a><span class="pipe">|</span><a href="http://www.focaloptics.com" title="主办单位：武汉焦点光学技术有限公司" target="_blank" >焦点光学</a><span class="pipe">|</span><a href="http://www.oecr.com" target="_blank">光电工程师社区</a> ( <a href="http://beian.miit.gov.cn/" target="_blank">鄂ICP备17021725号-1</a> <a href="http://www.beian.gov.cn/portal/registerSystemInfo?recordcode=42011102000821" target="_blank">鄂网安备42011102000821号</a> ) <span id="tcss"></span><script type="text/javascript" src="http://tcss.qq.com/ping.js?v=1eOg" charset="utf-8"></script><script type="text/javascript" reload="1">pgvMain({"discuzParams":{"r2":"1028778","ui":0,"rt":"plugin","pn":1,"qq":"000"},"extraParams":""});</script></p> <p class="xs0"> <span id="debuginfo"> Copyright 2015 光电工程师社区 版权所有 All Rights Reserved. </span> </p> </div> <div id="ftl" > <p>申明：本站为非盈利性公益个人网站，已关闭注册功能，本站所有内容均为网络收集整理，不代表本站立场。如您对某些内容有质疑或不快，请及时联系我们处理！ </p> </div> <div id="frt" > <div class="wp"> <p class="dd01"> © 2001-2022 <a href="http://www.oecr.com" target="_blank">光电工程师社区</a> 网站备案号：<a href="https://beian.miit.gov.cn/">鄂ICP备17021725号</a> 网站公安备案号：<a href="http://www.beian.gov.cn/portal/registerSystemInfo?recordcode=42011102000821">鄂42011102000821号</a> Powered by <a href="http://www.discuz.net" target="_blank">Discuz!</a> <em>X3.2</em> </p><p class="dd02">GMT+8, 2025-12-17 00:07 </p> </div> </div></div> </div> </div> <!--bottombg结束--> <script src="home.php?mod=misc&ac=sendmail&rand=1765901236" type="text/javascript"></script> <!--<div id="scrolltop"> <span hidefocus="true"><a title="返回顶部" onclick="window.scrollTo('0','0')" class="scrolltopa" ><b>返回顶部</b></a></span> </div> --> <div id="scrolltop"> <span hidefocus="true"><a title="返回顶部" onclick="window.scrollTo('0','0')" class="scrolltopa" ><b>返回顶部</b></a></span> </div> <script type="text/javascript">_attachEvent(window, 'scroll', function () { showTopLink(); });checkBlind();</script> <div id="discuz_tips" style="display:none;"></div> <script type="text/javascript"> var tipsinfo = '1028778|X3.2|0.6||0||0|7|1765901236|e7ff239a06850d1159a3f80331e57146|2'; </script> <script src="http://discuz.gtimg.cn/cloud/scripts/discuz_tips.js?v=1" type="text/javascript" charset="UTF-8"></script></body></html>